Glacial Acetic Acid

General Information:
CAS Number 64 - 19 - 7
EINECS Number 200 - 580 - 7
Chemical Name Acetic Acid
Chemical Classification Carboxylic Acid
Synonyms
Ethanoic acid; vinegar (a dilute solution of acetic acid); glacial acetic acid.
Formula C2H4O2
Molecular weight 60.05
Shipping Name Acetic Acid, Glacial
Codes / Label Flammable corrosive liquid, class - 8. Transport category - 2.
Hazardous Waste ID No. 5
Hazchem Code Not listed
UN Number 2789
Description Colorless liquid with strong vinegar like odor.
Product uses
In the manufacture of various acetates, acetyl compounds, cellulose acetate, acetate rayon, plastics and rubber, in tanning printing calico & dyeing silk; as preservative in foods; solvent for gums, resins, volatile oils.
   
Product Specifications:
Specifications Limits
Acetic Acid, Glacial, % w/w min. 99.50
Heavy metals (Pb) including iron, ppm 5.00
Boiling point, oC
117 - 119
Chloride (as Cl), ppm max.
15.00
Sulphates (as SO4"), ppm max 15.00
Residue on evaporation, % w/w max 00.02
Formic Acid, % w/w max. 00.25
Packaging 35 Kg. Jerry cans made of HDPE. Bulk, transport in dry and leak-proof SS Tankers / Containers.
Application
In the manufacture of cellulose acetate, acetate rayon; plastics & rubber in tanning; printing calico and drying silk; as preservative in food industries; as solvent and chemical intermediate.
   
This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should therefore, not be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our product is guaranteed under our General Conditions of Sale.
   
Material safety data sheet
(According to 91/155 EC)
   
1. Identification of the substance / preparation and of the company / undertaking:
Product details:
Trade name ACETIC ACID, GLACIAL
Chemical name/ formula ACETIC ACID, C2H4O2
Manufacturer / Supplier  
   
Kanoria Chemicals & Industries Ltd.

3407 GIDC Industrial Estate,
Ankleshwar 393 002 (Gujarat), India
Tel:+91 2646 668801-04
Fax: +91 2646 251816
Email: This email address is being protected from spambots. You need JavaScript enabled to view it. This e-mail address is being protected from spam bots, you need JavaScript enabled to view it
Web: http://www.kanoriachem.com
Kanoria Chemicals & Industries Ltd.

A-304/305/306, Universal Business Park,
Chandivali Farm Road, Off Saki Vihar Road,
Near Kamani Oil Mills, Saki Naka, Andheri (East),
Mumbai 400 072 (Maharashtra), India.
Tel: +91 22 28470216, 28470217
Fax: +91 22 28470235
Email: This email address is being protected from spambots. You need JavaScript enabled to view it. This e-mail address is being protected from spam bots, you need JavaScript enabled to view it
Further information obtainable from Information in case of emergency Safety Department
Tel: +91 2646 668869
   
2. Composition/ information on ingredients:
Description CAS Number EINECS Number
Acetic Acid 64-19-7 200-580-7
   
3. Hazard identification:
Hazard description
Flammable, corrosive liquid. Causes serious burn and serve irritation to skin, eyes and respiratory system. Ingestion may cause burning of mouth and stomach, vomiting and loss of conscious.
Chronic exposure May result in lung damages.
Carcinogenicity (NTP/IARC/OSHA) No
   
4. First-aid measures:
After inhalation
Remove to fresh air, restore breathing.
After skin contact
Flush with plenty of water at least for 15-20 minutes. Remove and decontaminate soiled clothing before reuse. In case of severe burns, get medical attention.
After eye contact
Flush opened eye with plenty of running water for at least 15-20 minutes. Get medical attention.
After swallowing
Do not induce vomiting. If conscious, give water, milk or milk of magnesia.
   
5. Fire-fighting measures:
Suitable extinguishing agents
Water spray, alcohol foam, and dry chemical powder,CO2
   
6. Accidental release measures:
Person-related safety precautions
Proper protective equipment and respiratory system. Eliminate sources of ignition.
Measures for cleaning/collecting
Shut off sources of ignition, no flares, smoking or flames in area. Stop leakage, if possible. Neutralize spill with soda ash or lime; containerize the waste for disposal according to item 13. Flush the area with water and send flush water to ETP.
   
7. Handling and storage:
Handling  
Information for safe handling
avoid breathing vapours, avoid contact with skin and eyes.
Information about fire and explosion
Flammable liquid; vapours may form explosive mixture with air. Closed containers, exposed to heat may explode.
Storage  
Requirements to be met by storerooms and receptacles
Store in tightly closed containers in a dry, cool, well-ventilated flammable liquid area. Keep away from strong oxidizing agents.
   
8. Exposure controls / protection:
64-19-7 Acetic Acid
PEL (OSHA)
10 mg/m3
TLV (ACGIH) Short term value : 15 mg/m3
Long term value: 10 mg/m3
Personal protective equipment Proper protective device.
Respiratory protection
Self-contained breathing apparatus with full-face piece, operated in positive pressure mode.
Protection of hands Acid resistant gloves.
Protection of Eye Safety glasses with face shield.
   
9. Physical and chemical properties:
General information:
Form
Liquid
Colour
Colourless
Odour Strong vinegar like odour
Change in condition  
Melting point 16oC
Boiling Point / Boiling range 118oC
Flash point: (CC) 43oC
Explosion Limits Upper 16 %; Lower : 4 %
Auto ignition temperature 426oC
Vapour pressure (mm Hg) 11 at 20oC
Vapour density (AIR = 1) 2.1
Specific gravity at 25oC 1.05
Evaporation rate & Ref < 1 (n-butyl acetate=1)
Solubility in water/ Miscibility with water at 25oC 100%
10. Stability & Reactivity:
This product is stable. Keep away from source of heat, open flames and other sources of ignition. Keep away from strong oxidizing agents, metals, alkali hydroxides anhydrides, permanganates, peroxides, ethanolamines, and alcohols.
   
Dangerous decomposition products CO & CO2 and incompletely burnt carbon products in black smoke.
   
11. Toxicological information:
Acute toxicity:
LD /LC50 values relevant for classification:
Oral LD 50 3310 mg/kg (Rat)
IV LD 50 525 mg/kg (Mouse)
SKN LD50 1060 mg/kg (Rabbit)
INHL LC50 5620 ppm/hr (Mouse)
Primary irritant effect:
On the skin Strong irritant
On the eyes Strong irritant
Sensitization Not known
   
12. Ecological information:
Environmental toxicity
Data not available
Environmental fate
Data not available
   
13. Disposal conditions:
Whatever cannot be recycled should be neutralized with soda ash or lime, absorbed in inert absorbent, containerized and transferred to appropriate and approved waste disposal facility. Dispose waste, containers and unused contents in accordance with official requirements.
   
14. Rransit information:
Shipping name ACETIC ACID, GLACIAL
UN Number 2789; Class: 8
Packing group II, DOT Label: Flammable corrosive liquid
   
15. Regulatory information:
Observe general safety regulations for handling flammable, corrosive chemicals.
   
16. Other information:
Kanoria Chemicals & Industries Limited provides the information contained herein in good faith, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.Kanoria chemicals & industries limited makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. accordingly, kanoria chemicals & industries limited will not be responsible for damages resulting from use of or reliance upon this information.
   
Department issuing MSDS: Safety Department
   
Date of Issue: 01-07-2012 Date of Revision: 30-06-2015
This document is valid for 03 years from the date of issue, and is bound to be canceled, if not revised on or before the date of revision.